1-Chloro- and l-Hydroxyphospholene-l-stilfides
نویسنده
چکیده
A mixture of the two isomers of 1-chlorophospholene-l-oxide, obtained by a one-step, high-yield procedure reported previously1, upon reaction with P4S10 was converted to a mixture of the two isomers of 1-chlorophospholene-l-sulfide which may be separated by spinning-band distillation. The thus obtained isomerically pure 1-chlorophospholene-1sulfides were hydrolyzed to the corresponding 1-hydroxyphospholene-l-sulfides. These, as well as the precursor chloro compounds, were characterized by iH, 13C, and 31P NMR, mass spectrometry, and IR.
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